The purpose of this study is to investigate the seismic ambient noise spectral anomalies that occur near gas reservoirs. These anomalies involve a significant spectral amplification of the vertical component for frequencies generally between 1.5 and 4 Hz and have been reported at various hydrocarbon sites worldwide. There are differing views on the mechanisms responsible for these anomalies. The guideline for this study is that many hydrocarbon reservoirs share a common geological feature: an anticline structure. It appears to cause site effects that influence the amplitude of the ambient noise wavefield. This research examines a dense real data set of ambient noise recorded at the Chémery underground gas storage site in France. The analysis identifies stable spectral anomalies between 1.2 and 2.4 Hz that are correlated to the position of the anticline structure, which also corresponds to the position of the gas bubble. We use a beamforming technique to study the composition and the origin of the ambient noise, and show that the variations of the spectral anomalies over time are correlated to changes in the source wavefield. Finally, we perform numerical simulations of Rayleigh wave propagation within a realistic 3-D velocity model of the Chémery site, while using source distributions directly extracted from real data analysis. The comparison of the simulated anomalies with real data yields a satisfactory qualitative fit. We conclude that the fundamental-mode Rayleigh wave site effect on the anticline is the main mechanism of the spectral anomaly.